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Cyclombandakamine A2
- Family: Plantae - Ancistrocladaceae
- Kingdom: Plantae
-
Class: Alkaloid
- Subclass: Naphthylisoquinoline Alkaloid
Canonical Smiles | COc1cc2O[C@]34c5c(c2c2c1[C@@H](C)N(C)[C@@H](C2)C)ccc(c5C(=O)C[C@]4(C)Oc1c3cc(c2c(O)cc(c3c2C[C@H](C)N([C@@H]3C)C)OC)c2c1c(OC)cc(c2)C)OC |
---|---|
InChI | InChI=1S/C50H54N2O8/c1-23-15-29-30(43-31-17-24(2)51(7)26(4)41(31)38(57-11)20-34(43)53)19-33-48(45(29)37(16-23)56-10)60-49(6)22-35(54)46-36(55-9)14-13-28-44-32-18-25(3)52(8)27(5)42(32)39(58-12)21-40(44)59-50(33,49)47(28)46/h13-16,19-21,24-27,53H,17-18,22H2,1-12H3/t24-,25+,26+,27+,49-,50-/m0/s1 |
InChIKey | HNCYEGHHOCVPLZ-AAFKBUOQSA-N |
Formula | C50H54N2O8 |
HBA | 10 |
HBD | 1 |
MW | 810.99 |
Rotatable Bonds | 5 |
TPSA | 99.16 |
LogP | 9.47 |
Number Rings | 10 |
Number Aromatic Rings | 5 |
Heavy Atom Count | 60 |
Formal Charge | 0 |
Fraction CSP3 | 0.42 |
Exact Mass | 810.39 |
Number of Lipinski Rule Violations | 2 |
# | Species | Family | Kingdom | NCBI Taxonomy ID |
---|---|---|---|---|
1 | Ancistrocladus sp. | Ancistrocladaceae | Plantae | 300538 |
2 | Ancistrocladus liana | Ancistrocladaceae | Plantae | 63071 |
3 | Ancistrocladus liana | Ancistrocladaceae | Plantae | 63071 |
4 | Ancistrocladus liana | Ancistrocladaceae | Plantae | 63071 |
Showing of synonyms
Cyclombandakamine A2
- Lombe BK, Bruhn T, et al. (2017). Antiprotozoal spirombandakamines A1 and A2, fused naphthylisoquinoline dimers from a Congolese Ancistrocladus plant. Organic letters,2017, 19(24), 6740-6743. [View] [PubMed]
- Lombe BK, Bruhn T, et al. (2017). Cyclombandakamines A1 and A2, oxygen-bridged naphthylisoquinoline dimers from a Congolese Ancistrocladus liana.. Organic letters,2017, 19(6), 1342-1345. [View] [PubMed]
- Lombe BK, Feineis D, et al. (2021). Spirombandakamine A3 and Cyclombandakamines A8 and A9, polycyclic naphthylisoquinoline dimers, with antiprotozoal activity, from a congolese ancistrocladus plant. Journal of natural products,2021, 84(4), 1335-1344. [View] [PubMed]
Pubchem:
132608472
No compound-protein relationship available.
SMILES: C1CNCc(c12)cccc2-c(c3)c(cccc4)c4c(c3C567)OC5CC(=O)c8c6c(ccc8)c9c1c(ccc9O7)CNCC1
Level: 1
Mol. Weight: 810.99 g/mol
SMILES: c1cccc(cc2)c1c(c2C345)OC3CC(=O)c6c4c(ccc6)c7c8c(ccc7O5)CNCC8
Level: 0
Mol. Weight: 810.99 g/mol
SMILES: C1CNCc(c12)cccc2
Level: 0
Mol. Weight: 810.99 g/mol
Antimalarial
Antiprotozoal
Absorption
- Caco-2 (logPapp)
- -5.45
- Human Oral Bioavailability 20%
- Non-Bioavailable
- Human Intestinal Absorption
- Non-Absorbed
- Madin-Darby Canine Kidney
- 614.610
- Human Oral Bioavailability 50%
- Non-Bioavailable
- P-Glycoprotein Inhibitor
- Inhibitor
- P-Glycoprotein Substrate
- Substrate
- Skin Permeability
- 81032.72
Distribution
- Blood-Brain Barrier (CNS)
- -
- Blood-Brain Barrier
- Non-Penetrable
- Fraction Unbound (Human)
- 1.120
- Plasma Protein Binding
- 70.92
- Steady State Volume of Distribution
- -
Metabolism
- Breast Cancer Resistance Protein
- Inhibitor
- CYP 1A2 Inhibitor
- Non-Inhibitor
- CYP 1A2 Substrate
- Substrate
- CYP 2C19 Inhibitor
- Non-Inhibitor
- CYP 2C19 Substrate
- Non-Substrate
- CYP 2C9 Inhibitor
- Non-Inhibitor
- CYP 2C9 Substrate
- Substrate
- CYP 2D6 Inhibitor
- Non-Inhibitor
- CYP 2D6 Substrate
- Non-Substrate
- CYP 3A4 Inhibitor
- Non-Inhibitor
- CYP 3A4 Substrate
- Substrate
- OATP1B1
- Non-Inhibitor
- OATP1B3
- Inhibitor
Excretion
- Clearance
- 9.980
- Organic Cation Transporter 2
- Non-Inhibitor
- Half-Life of Drug
- -
Toxicity
- AMES Mutagenesis
- Safe
- Avian
- Toxic
- Bee
- Toxic
- Bioconcentration Factor
- -1886.120
- Biodegradation
- Safe
- Carcinogenesis
- Safe
- Crustacean
- Toxic
- Liver Injury I (DILI)
- Safe
- Eye Corrosion
- Safe
- Eye Irritation
- Safe
- Maximum Tolerated Dose
- -0.270
- Liver Injury II
- Toxic
- hERG Blockers
- Toxic
- Daphnia Maga
- 4.820
- Micronucleos
- Toxic
- NR-AhR
- Safe
- NR-AR
- Safe
- NR-AR-LBD
- Safe
- NR-Aromatase
- Safe
- NR-ER
- Safe
- NR-ER-LBD
- Safe
- NR-GR
- Safe
- NR-PPAR-gamma
- Safe
- NR-TR
- Toxic
- T. Pyriformis
- -147069184.420
- Rat (Acute)
- 3.040
- Rat (Chronic Oral)
- 1.640
- Fathead Minnow
- 185650.330
- Respiratory Disease
- Toxic
- Skin Sensitisation
- Safe
- SR-ARE
- Safe
- SR-ATAD5
- Safe
- SR-HSE
- Safe
- SR-MMP
- Toxic
- SR-p53
- Toxic
General Properties
- Boiling Point
- 16536942.740
- Hydration Free Energy
- -2.920
- Log(D) at pH=7.4
- 4.350
- Log(P)
- 7.1
- Log S
- -6.23
- Log(Vapor Pressure)
- -544498.83
- Melting Point
- 226.81
- pKa Acid
- -3912.75
- pKa Basic
- 1.81
Protein Name | UniProt ID | Entry Name | Species | #Pharmacophore Points | Probability (0.7 ≤ Tversky Score ≤ 1.0) |
---|---|---|---|---|---|
Nicotinate-nucleotide--dimethylbenzimidazole phosphoribosyltransferase | Q05603 | COBT_SALTY | Salmonella typhimurium | 3 | 0.8811 |
Nicotinate-nucleotide--dimethylbenzimidazole phosphoribosyltransferase | Q05603 | COBT_SALTY | Salmonella typhimurium | 3 | 0.8811 |
Protein farnesyltransferase/geranylgeranyltransferase type-1 subunit alpha | Q04631 | FNTA_RAT | Rattus norvegicus | 3 | 0.8437 |
Protein farnesyltransferase/geranylgeranyltransferase type-1 subunit alpha | Q04631 | FNTA_RAT | Rattus norvegicus | 3 | 0.8437 |
Protein farnesyltransferase/geranylgeranyltransferase type-1 subunit alpha | Q4WP27 | Q4WP27_ASPFU | Aspergillus fumigatus | 3 | 0.8221 |
Protein farnesyltransferase/geranylgeranyltransferase type-1 subunit alpha | Q4WP27 | Q4WP27_ASPFU | Aspergillus fumigatus | 3 | 0.8221 |
HTH-type transcriptional regulator QacR | P0A0N4 | QACR_STAAU | Staphylococcus aureus | 3 | 0.8097 |
HTH-type transcriptional regulator QacR | P0A0N4 | QACR_STAAU | Staphylococcus aureus | 3 | 0.8097 |
Norsolorinic acid synthase | Q12053 | AFLC_ASPPU | Aspergillus parasiticus | 3 | 0.7788 |
Norsolorinic acid synthase | Q12053 | AFLC_ASPPU | Aspergillus parasiticus | 3 | 0.7788 |
Lactotransferrin | P24627 | TRFL_BOVIN | Bos taurus | 3 | 0.7731 |
Lactotransferrin | P24627 | TRFL_BOVIN | Bos taurus | 3 | 0.7731 |
Epidermal growth factor receptor | P00533 | EGFR_HUMAN | Homo sapiens | 3 | 0.7680 |
Epidermal growth factor receptor | P00533 | EGFR_HUMAN | Homo sapiens | 3 | 0.7680 |
Riboflavin synthase | P0AFU8 | RISA_ECOLI | Escherichia coli | 4 | 0.7668 |
Riboflavin synthase | P0AFU8 | RISA_ECOLI | Escherichia coli | 4 | 0.7668 |
Lactotransferrin | P24627 | TRFL_BOVIN | Bos taurus | 2 | 0.7586 |
Lactotransferrin | P24627 | TRFL_BOVIN | Bos taurus | 2 | 0.7586 |
NADPH-dependent oxidoreductase 2-alkenal reductase | Q39172 | AER_ARATH | Arabidopsis thaliana | 3 | 0.7473 |
NADPH-dependent oxidoreductase 2-alkenal reductase | Q39172 | AER_ARATH | Arabidopsis thaliana | 3 | 0.7473 |
HTH-type transcriptional regulator QacR | P0A0N3 | QACR_STAAM | Staphylococcus aureus | 3 | 0.7438 |
HTH-type transcriptional regulator QacR | P0A0N3 | QACR_STAAM | Staphylococcus aureus | 3 | 0.7438 |
Carbonic anhydrase 2 | P00918 | CAH2_HUMAN | Homo sapiens | 3 | 0.7388 |
Carbonic anhydrase 2 | P00918 | CAH2_HUMAN | Homo sapiens | 3 | 0.7388 |
Acetylcholinesterase | P21836 | ACES_MOUSE | Mus musculus | 3 | 0.7375 |
Acetylcholinesterase | P21836 | ACES_MOUSE | Mus musculus | 3 | 0.7375 |
Seminal ribonuclease | P00669 | RNS_BOVIN | Bos taurus | 3 | 0.7335 |
Seminal ribonuclease | P00669 | RNS_BOVIN | Bos taurus | 3 | 0.7335 |
Cytosolic purine 5'-nucleotidase | P49902 | 5NTC_HUMAN | Homo sapiens | 2 | 0.7333 |
Cytosolic purine 5'-nucleotidase | P49902 | 5NTC_HUMAN | Homo sapiens | 2 | 0.7333 |
Glucose-1-phosphate thymidylyltransferase | Q9HU22 | Q9HU22_PSEAE | Pseudomonas aeruginosa | 3 | 0.7293 |
Glucose-1-phosphate thymidylyltransferase | Q9HU22 | Q9HU22_PSEAE | Pseudomonas aeruginosa | 3 | 0.7293 |
Basic phospholipase A2 VRV-PL-VIIIa | P59071 | PA2B8_DABRR | Daboia russelii | 2 | 0.7221 |
Carbonic anhydrase 2 | P00918 | CAH2_HUMAN | Homo sapiens | 3 | 0.7221 |
Carbonic anhydrase 2 | P00918 | CAH2_HUMAN | Homo sapiens | 3 | 0.7221 |
Basic phospholipase A2 VRV-PL-VIIIa | P59071 | PA2B8_DABRR | Daboia russelii | 2 | 0.7221 |
Cathepsin S | P25774 | CATS_HUMAN | Homo sapiens | 3 | 0.7183 |
Cathepsin S | P25774 | CATS_HUMAN | Homo sapiens | 3 | 0.7183 |
Lactotransferrin | P24627 | TRFL_BOVIN | Bos taurus | 2 | 0.7159 |
Lactotransferrin | P24627 | TRFL_BOVIN | Bos taurus | 2 | 0.7159 |