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19 Families
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| # | Family | Kingdom | #Compounds | #Species |
| 1 | Salicaceae | Plantae | 19 | 3 |
| 2 | Salvadoraceae | Plantae | 3 | 1 |
| 3 | Sapindaceae | Plantae | 73 | 9 |
| 4 | Sapotaceae | Plantae | 116 | 12 |
| 5 | Sargassaceae | Plantae | 13 | 3 |
| 6 | Sargassaceae-Fucaceae | Chromista | 27 | 2 |
| 7 | Scrophulariaceae | Plantae | 55 | 14 |
| 8 | Scytosiphonaceae | Plantae | 2 | 2 |
| 9 | Simaroubaceae | Plantae | 26 | 3 |
| 10 | Sisymbrieae | Plantae | 6 | 1 |
| 11 | Solanaceae | Plantae | 170 | 24 |
| 12 | Sordariaceae | Plantae | 3 | 1 |
| 13 | Sphacelariaceae | Chromista | 4 | 1 |
| 14 | Sphaerococcaceae | Plantae | 4 | 1 |
| 15 | Spongiidae | Animalia | 3 | 1 |
| 16 | Sporocadaceae | Fungi | 3 | 1 |
| 17 | Sporormiaceae | Fungi | 15 | 3 |
| 18 | Sterculiaceae | Plantae | 16 | 4 |
| 19 | Streptomycetaceae | Monera | 7 | 3 |
